Greatest Hits Live gathers ten live recordings by Ace Frehley, rounded off with two studio tracks. The set runs across his whole repertoire: KISS songs such as "Cold Gin", "Shock Me", "Deuce" and "Rocket Ride" sit next to solo material like "Rip It Out", "New York Groove" and "Rock Soldiers". The live recordings come from London and Chicago, while the closing studio tracks "One Plus One" and "Give It To Me Anyway" were left over from the earlier compilation Loaded Deck. The album originally appeared in 2006 on Megaforce Records.

This edition is a 2-LP on orange vinyl.